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INVESTIGATION OF INTER-PHASE BOUNDARIES IN POLYCRYSTALLINE FILMS OF FERROELECTRIC OXIDES OF PEROVSKITE TYPE

N. V. Mukhin, Ph.D. (Tech.), associate professor, senior researcher, LETI, Saint Petersburg, Russia; This email address is being protected from spambots. You need JavaScript enabled to view it.
M. V. Rudenko, researcher, BSUIR, Minsk, Belarus; This email address is being protected from spambots. You need JavaScript enabled to view it.
N. V. Gaponenko, Dr. Sc. (Phys. and Math.), full professor, BSUIR, Minsk, Belarus; This email address is being protected from spambots. You need JavaScript enabled to view it.
T. V. Gordinskaya, student, LETI, Saint Petersburg, Russia; This email address is being protected from spambots. You need JavaScript enabled to view it.
A. V. Ermachikhin, Ph.D. (Phys. and Math.), associate professor, senior researcher, RSREU, Ryazan, Russia; This email address is being protected from spambots. You need JavaScript enabled to view it.
V. G. Litvinov, Ph.D. (Phys. and Math.), associate professor, RSREU, Ryazan, Russia; This email address is being protected from spambots. You need JavaScript enabled to view it.

Generalized model concepts describing the formation of dispersed inclusions of new phases of different stoichiometric composition at the interfaces in polycrystalline films of multicomponent ferroelectric oxides due to the processes of bulk diffusion, grain boundary segregation and interaction with the substrate are described. The aim of the work is an experimental study of the formation of inclusions of «impurity» phases in ferroelectric oxides on the example of polycrystalline films of lead titanate zirconate and strontium bismuth tantalate.

Key words: interfaces, complex oxides, polycrystalline films, phase formation, nonstoichiometry.

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